Physical organic chemistry (Issacs, Neil S.)
نویسندگان
چکیده
منابع مشابه
Physical organic chemistry
Physical organic chemistry – the study of the interplay between structure and reactivity in organic molecules – underpins organic chemistry, and we cannot imagine organic chemistry as a subject without knowledge of mechanism and reactivity. It is sometimes thought that the golden age of ‘physical organic chemistry’ was in the 20th century, when systematic information about mechanism first burst...
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ion moval of an atom (neutral or charged) from a molecular entity. For example: A chemical reaction or transformation, the main feature of which is the bimolecular reCH3COCH3 + (i-C3H7)2N(CH&OCH;?>+ (i-C3H7)2NH (proton abstraction from acetone) CH4 + C1' H3C' + HCl (hydrogen abstraction from methane) acceptor number (AN)
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“Physical-organic chemistry” is not really about physical chemistry, organic chemistry, or even chemistry. It is a strategy for the design of programs in experimental scientific research – admittedly, a strategy most highly developed for research involving organic molecules as components – that offers a general, and remarkably versatile, method for tackling complex problems. The idea underlying...
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The challenges to obtaining chemical-scale information on the molecules of neuroscience are considerable. Most targets are complex integral membrane proteins that are not amenable to direct structural characterization. However, by combining the tools of organic synthesis, molecular biology, and electrophysiology, rational and systematic structure-function studies can be performed in what we hav...
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A perspective on the development of mechanistic carbene chemistry is presented. The author will point out questions that have been answered, and a next generation of questions will be proposed.
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1988
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed065pa335.2